RCMP responded to a collision involving two cars on Highway 325 in Whynotts Settlement, N.S., on Monday at 9 p.m.
Paramedics and the Oakhill Volunteer Fire Department also responded.
READ MORE: 2 women dead following 2-vehicle collision in Pictou County
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Police said a 22-year-old man from Hebbs Cross, the driver and lone occupant of one vehicle, was transported to hospital with life-threatening injuries. The driver and lone occupant of the other car, a 25-year-old woman from Maitland, was also transported to hospital with minor injuries.
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An RCMP collision analyst attended the scene. Highway 325 was closed for several hours but has since reopened.
Police said the investigation is ongoing.
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